Secondly quantized multi-configurational approach for atomic databases

Details Secondly quantized multi-configurational approach for atomic databases Secondly quantized multi-configurational approach for atomic databases

2004-05-14

arxiv.org/abs/physics/0405076v1

NIST Special Publication 926 (1998) 128-131

Physics

Atomic Physics

Scientific paper

General method is suggested to find non-relativistic and relativistic matrix elements of one- and two-electron operators for any number of open shells in atom, requiring neither coefficients of fractional parentage nor unit tensors. It is based on second quantization in coupled tensorial form, angular momentum theory in orbital, spin and quasispin spaces and generalized graphical technique. All matrix elements (diagonal and non-diagonal with respect to configurations) differ then only by projections of quasispin of separate shells and are expressed via completely reduced (in three spaces) matrix elements of second quantization operator and its products. Thus, all matrix elements are treated uniformly. This approach allows one to generate fairly accurate databases of atomic parameters.

Affiliated with

Also associated with

No associations

Rating

Secondly quantized multi-configurational approach for atomic databases does not yet have a rating. At this time, there are no reviews or comments for this scientific paper.

If you have personal experience with Secondly quantized multi-configurational approach for atomic databases, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Secondly quantized multi-configurational approach for atomic databases will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFWR-SCP-O-671923