Computer Science – Performance
Scientific paper
Jul 2000
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2000came.work...42b&link_type=abstract
Concepts and Approaches for Mars Exploration, p. 42
Computer Science
Performance
Mars Surface Samples, Organic Materials, Gas Chromatography, Mass Spectrometers, In Situ Measurement, Microanalysis
Scientific paper
On Earth, the molecules which participated in the emergence of life about 4 Ga ago have been erased by plate tectonics, the permanent presence of running water, unshielded solar ultraviolet radiation and by oxygen produced by life. Since the environment of the early Mars about 3.5-4 Ga ago was probably very close to that of the early Earth, life might have emerged on Mars as well and might give us some insight into the prebiotic chemistry that took place on Earth about 4 Ga ago. Furthermore, there is a possibility that life still exists on Mars, protected from the harsh environment in some specific locales. In order to search for life on Mars, one should look for potential biogenic markers such as organic matter and inorganic signatures (microfossils, biominerals, biogenic etching, isotopic fingerprints...) which have different degrees of resistance to the Martian environment. As biomarkers could be organic or inorganic in nature, complete organic and mineral analyses should therefore be conducted in parallel on the same sets of samples, going from the least destructive to the most destructive technique of micro-analysis. Furthermore, in situ analyses should be complemented by high precision and high sensitivity laboratory measurements of returned Martian samples. Due to the very oxidized Martian environment, organic molecules should be searched for in protected sites, either surface boulders or near sub-surface, in layers deep enough for avoiding the oxidizing effect of the atmosphere. Molecules that should be looked for include low and high molecular weight organics (like alkanoic acids, peroxiacids, PAHs and amino acids, respectively), and macromolecular com-pounds like kerogens or kerogen-like materials. Previous in situ analyses were performed using pyrolysis systems which allow to detect organic compounds but do not always permit the identification of individual molecules. New possible analytical solutions could include gas chromatography-based techniques coupled with a mass spectrometer using multi GC columns systems, including columns able to separate enantiomers, chemical derivatization cells (using new derivatization schemes in particular for amino acid analysis), high performance liquid chromatography and supercritical fluid chromatography.
Brack André
Commeyras Auguste
Derenne Sylvie
Despois Didier
Dhamelincourt P.
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