Rotational structure of weakly bound molecular ions

Details Rotational structure of weakly bound molecular ions Rotational structure of weakly bound molecular ions

2009-10-30

arxiv.org/abs/0910.5743v1

J. At. Mol. Sci. 1, 41 (2010)

Physics

Atomic Physics

4 pages, 1 figure

Scientific paper

10.4208/jams.101009.110209a

Relying on the quantization rule of Raab and Friedrich [Phys. Rev. A (2009) in press], we derive simple and accurate formulae for the number of rotational states supported by a weakly bound vibrational level of a diatomic molecular ion. We also provide analytic estimates of the rotational constants of any such levels up to threshold for dissociation and obtain a criterion for determining whether a given weakly bound vibrational level is rotationless. The results depend solely on the long-range part of the molecular potential.

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