Physics
Scientific paper
Jun 2009
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2009mss..confemj03r&link_type=abstract
"International Symposium On Molecular Spectroscopy, 64th Meeting, Held 22-26 June, 2009 at Ohio State University. http://molspec
Physics
Matrix/Condensed Phase
Scientific paper
Rotational spectra of carbon monoxide (^{12}C^{16}O and ^{13}C^{16}O) solvated with N=2 to 7 para-hydrogen (pH_2) molecules were studied by high resolution Fourier transform microwave spectroscopy. Infrared spectra of (pH_2)_N-CO clusters have previously been reported by Moroni et al. It is expected that the end-over-end rotational frequency decreases from N=2 to N=6, then increases with the addition of the next several helium atoms; this could indicate a significant decoupling of pH_2 density from CO rotation. By measuring the microwave transitions of these clusters we are able to separate the rotational and vibrational contributions to the rovibrational line positions. The trend of the pure rotational frequencies with increasing N-value will be presented.
S. Moroni, M. Botti, S. De Palo, A. R. W. McKellar, J. Chem. Phys., 122, 094314 (2005).
Jäger Wolfgang
Raston Paul L.
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