Rotational inelastic cross sections for OCS-Ar, OCS-He, OCS-H2 collisions - A comparison between theory and experiment

Physics – Chemical Physics

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Carbon, Interstellar Radiation, Molecular Collisions, Oxygen, Pressure Broadening, Sulfur, Argon, Cross Sections, Helium, Hydrogen, Interstellar Matter, Laser Spectroscopy, Molecular Rotation, Spectral Line Width

Scientific paper

The experimental determination of absorption line profiles for OCS nu3 vibrational transitions broadened by collisions with Ar, He, and H3 buffer gases is reported. The experimental method using diode laser spectroscopy in the five micron region is described. The data are compared with theoretical values obtained using intermolecular potentials previously suggested for these systems and infinite order sudden approximation molecular scattering calculations.

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