Role of screw axes in dissolution of willemite

Details Role of screw axes in dissolution of willemite Role of screw axes in dissolution of willemite

Apr 1993

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993gecoa..57.1649l&link_type=abstract

Geochimica et Cosmochimica Acta, vol. 57, Issue 8, pp.1649-1655

Physics

Scientific paper

Static dissolution on the basal plane {0001} of willemite in extremely acid aqueous solutions has produced the curved etch hillocks, indicating anisotropic <10 0> dissolution. This abnormal dissolution behavior cannot be attributed to defects or active lattice site density, which are equal for all {10 0} planes, but can be reasonably explained if the detachment of the active lattice sites (namely, ZnO 4 ) proceeds along the alternate screw axes via a closest neighbor path. The effects of alloyed impurities, etchant variety, and pH value on the formation of etch hillocks are discussed.

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