Renner-Teller effects in HCO+ dissociative recombination

Details Renner-Teller effects in HCO+ dissociative recombination Renner-Teller effects in HCO+ dissociative recombination

2006-02-04

arxiv.org/abs/physics/0602027v2

Physics

Atomic Physics

11 pages

Scientific paper

A theoretical description of the dissociative recombination process for the HCO+ ion suggests that the nonadiabatic Renner-Teller coupling between electronic and vibrational degrees of freedom plays an important role. This finding is consistent with a recent study of this process for another closed-shell molecule, the H3+ ion, where Jahn-Teller coupling was shown to generate a relatively high rate. The cross section obtained here for the dissociative recombination of HCO+exhibits encouraging agreement with a merged-beam experiment.

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