Renner-Teller Effect on Dissociative Electron Attachments to Carbon Dioxide

Physics – Chemical Physics

Scientific paper

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14 pages, 4 figures

Scientific paper

Stereo-dynamics of dissociative electron attachments to CO_2 is investigated by the O^- anion velocity imaging experiments combined with the R-matrix calculations. ^2{\Pi}_g as a Feshbach resonant state of CO_2^- is confirmed to play roles in the dissociations around 8.0 eV. We find that the dynamic evolutions of the Renner-Teller effect lead to the dramatically different anisotropic O^- momentum distributions.

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