Remeasurement of the rate constant and branching ratio for the N2(+) + O reaction

Details Remeasurement of the rate constant and branching ratio for the N2(+) + O reaction Remeasurement of the rate constant and branching ratio for the N2(+) + O reaction

Mar 1988

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1988p%26ss...36..307k&link_type=abstract

Planetary and Space Science (ISSN 0032-0633), vol. 36, March 1988, p. 307-310. USAF-supported research.

Physics

7

Atmospheric Chemistry, Molecular Ions, Nitrogen, Oxygen Atoms, Reaction Kinetics, Chemical Reactions, Dayglow, Photoionization, Thermosphere

Scientific paper

In order to explore the discrepancy between the currently accepted thermospheric N2(+) model and measured values, the rate constant and branching ratio for the thermospherically important N2(+) + O reaction have been remeasured in a flowing afterglow. A rate constant of 1.8 (+ or - 0.7) x 10 to the -10th cu cm/s and a branching ratio of NO(+):O(+) = 90(+ or - 3):10(+ or - 3) are found, in good agreement with previous measurements. Implications of the findings for atmospheric models are considered.

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