Relativistic oscillator strengths for the Cs isoelectronic sequence and collapse of f and d orbitals.

Details Relativistic oscillator strengths for the Cs isoelectronic sequence and collapse of f and d orbitals. Relativistic oscillator strengths for the Cs isoelectronic sequence and collapse of f and d orbitals.

Jun 1987

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1987jqsrt..37..581m&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 37, issue 6, pp. 581-589

Physics

11

Oscillator Strengths:Cesium

Scientific paper

Model potential calculations have been performed to investigate the influence of valence-core electron exchange on oscillator strengths in the Cs isoelectronic sequence. It is demonstrated that inclusion of valence-core electron exchange in the model potential calculations of oscillator strengths for transitions involving orbitals which undergo the collapse phenomenon (usually d or f orbitals) is important and may modify the character of the transition (emisson or absorption) due to the change in the relative positions of the states involved.

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