Relative transition probabilities in the A-X system of OD

Physics

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Atmospheric Chemistry, Deuterium Compounds, Hydroxyl Emission, Transition Probabilities, Air Pollution, Branching (Physics), Dye Lasers, Fluorescence, Molecular Rotation, Wave Functions

Scientific paper

Branching ratios for emission from nu prime = 0, 1 and 2 of the A 2-Sigma(+) state of OD have been measured using frequency-doubled, tunable dye laser excitation. The six independent ratios so obtained are used to assess calculations incorporating an electronic transition moment varying linearly with internuclear distance. Calculations of the rotational dependence of the transition probabilities in OD, and comments on some recent OH investigations are included.

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