Relative Einstein coefficients and dipole moments of the ? transitions measured in oxygen atom recombination accompanied by radiation

Details Relative Einstein coefficients and dipole moments of the ? transitions measured in oxygen atom recombination accompanied by radiation Relative Einstein coefficients and dipole moments of the ? transitions measured in oxygen atom recombination accompanied by radiation

Apr 1996

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996jphb...29.1351f&link_type=abstract

Journal of Physics B: Atomic, Molecular, and Optical Physics, Volume 29, Issue 7, pp. 1351-1367 (1996).

Physics

5

Scientific paper

Spectra accompanying oxygen atom recombination have been measured in the 280 - 600 nm spectral range, at all-0953-4075/29/7/016/img2 and approximately all-He and all-0953-4075/29/7/016/img3 baths with 2 nm spectral resolution and an accuracy of several per cent. Emission bands from the 0953-4075/29/7/016/img4 and 0953-4075/29/7/016/img5 vibronic levels have been observed and assigned by a simulation procedure. Intensities of individual bands, relative Einstein coefficients, relative transition moments and vibronic level populations have been determined. The population profiles of the 0953-4075/29/7/016/img6 and 0953-4075/29/7/016/img7 vibronic levels depend strongly on the relative 0953-4075/29/7/016/img2 concentration. A non-monotonic dependence of the 0953-4075/29/7/016/img9 transition moment with internuclear distance in its 0.136 - 0.153 nm range has been found. The mechanism and kinetics of population and decay of vibronic levels of the molecular oxygen ungerade states and night airglow on Earth and Venus are discussed.

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