Relating inferred HNO3 flux values to the denitrification of the 1999-2000 Arctic vortex

Physics

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Atmospheric Composition And Structure: Aerosols And Particles (0345, 4801), Atmospheric Composition And Structure: Cloud Physics And Chemistry, Atmospheric Composition And Structure: Middle Atmosphere-Composition And Chemistry

Scientific paper

Extensive populations of large HNO3-containing particles were observed in situ in the 1999-2000 Arctic winter vortex. Assuming nitric acid trihydrate (NAT) composition, the associated values of instantaneous gravitational flux of HNO3 are between 1.108 and 5.1010 molec cm-3 km day-1 and are the largest ever derived from in situ measurements. The relationship between these observed population and observed denitrification in the 1999-2000 Arctic vortex developed using constraints of NAT formation and sedimentation. This analysis of the 1999-2000 winter provides a useful guide to interpreting future observations of polar stratospheric clouds and denitrification in the polar regions.

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