Regeneration of Fe(II) during EIFeX and SOFeX

Mathematics – Logic

Scientific paper

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Oceanography: Biological And Chemical: Chemical Speciation And Complexation, Oceanography: Biological And Chemical: Biogeochemical Cycles, Processes, And Modeling (0412, 0414, 0793, 1615, 4912), Oceanography: General: Diurnal, Seasonal, And Annual Cycles (0438), Oceanography: General: Arctic And Antarctic Oceanography (9310, 9315)

Scientific paper

Investigations into Fe(II) cycling during two Southern Ocean mesoscale iron enrichment experiments, SOFeX and EIFeX, clearly show the importance of Fe(II) to iron speciation during these experiments. In both cases the added Fe(II) persisted significantly longer than its expected oxidation time indicating a significant Fe reduction process at work. During EIFeX diel studies showed a strong photochemically induced cycle in Fe(II) production in sunlit surface waters. Our results suggest that the photochemical cycling of iron may also be important in unfertilized waters of the Southern Ocean.

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