Rate constant for quenching of CO2(010) by atomic oxygen

Details Rate constant for quenching of CO2(010) by atomic oxygen Rate constant for quenching of CO2(010) by atomic oxygen

Apr 1993

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1993georl..20..727p&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 20, no. 8, p. 727-729.

Physics

29

Carbon Dioxide, Molecular Interactions, Oxygen Atoms, Quenching, Reaction Kinetics, Infrared Absorption, Molecular Oscillations, Molecular Relaxation, Ozone, Photolysis

Scientific paper

The rate of quenching of CO2(010) by O(3P) has been measured at room temperature by a temperature-jump method. The rate constant value obtained is in good agreement with a previous room-temperature measurement based on steady-state analysis of a hollow-cathode discharge in CO2. The results of fitting the room-temperature result to trajectory calculations with a curve-crossing (Nikitin) energy-transfer mechanism lead to the conclusion that the quenching rate constant should increase only slowly with increasing temperature.

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