Rare earth and trace element geochemistry of metabasalts from the Point Sal ophiolite, California

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Scientific paper

The Point Sal ophiolite, California, contains a volcanic pile of pillowed and massive basalts and keratophyres that exhibit a downward change in metamorphic facies, i.e., zeolite to greenschist. Analyses of 14 stratigraphically sequential lavas reveals the existence of three lava types: (1) highly fractionated plagioclase phyric lavas at the base of the lava pile; (2) clinopyroxene-plagioclase phyric lavas at different eruptive levels throughout the pile, and (3) olivine-clinopyroxene phyric lavas (low ΣREE) in the midst of the eruptive suite. The upper portion of the lava pile contains lavas with chondritic to slightly light-REE-depleted profiles (La = 3.5-13.0× chondrite) and negative Ce anomalies. The lower part of the lava pile contains lavas with light-REE-depleted profiles (La = 1.7-28.0× chondrite), negative Eu anomalies, but no negative Ce anomalies. Application of fractionation laws to the olivine-clinopyroxene phyric lavas (approximations of initial mantle melts) verifies that the fractionation process involved olivine-clinopyroxene and plagioclase. Consideration of this and the eruptive sequence allows semiquantitative verification of an origin for the Point Sal lavas by low-pressure fractionation of multiple chambers of olivine basalt.

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