Raman spectroscopy of gases with a Fourier transform spectrometer - The spectrum of D2

Physics – Optics

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Deuterium, Fourier Transformation, Gas Spectroscopy, Incoherent Scattering, Laser Spectroscopy, Raman Spectroscopy, Argon Lasers, Helium-Neon Lasers, High Resolution, Hydrogen, Molecular Spectra

Scientific paper

Fourier transform spectrometry (FTS) is presently used to record the spontaneous incoherent laser Raman spectra of gases. The high resolution, sensitivity, calibration accuracy and spectral coverage achieved demonstrate the viability of FTS for Raman spectroscopy. Attention is given to the coefficients obtained by fitting measurements obtained from the spectrum of D2, containing both v = 0-0 and 1-0 transitions, to the Dunham (1932) expansion of the vibration-rotation energy levels.

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