Raising of Discrete Levels into the Far Continuum

Details Raising of Discrete Levels into the Far Continuum Raising of Discrete Levels into the Far Continuum

Jun 1971

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1971phrvl..26.1521d&link_type=abstract

Physical Review Letters, vol. 26, Issue 25, pp. 1521-1525

Physics

142

Scientific paper

Broad peaks observed in the photoabsorption spectra of rare earths ~10-20 eV above the 4d edge are attributed to transitions 4d104fN-->4d94fN+1. Exchange interaction splits the 4d94fN+1 configuration and raises some multiplets by ~20 eV. Autoionization to 4d9-4fNɛf broadens the high levels. The interpretation extends to p-->d processes observed in the absorption of synchrotron light by transition elements.

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