Radiative lifetimes of 6sns 3S1 and 6snd 3D1 excited states of Hg I

Physics

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Oscillator Strengths, Lifetimes, Transition Moments, Laser Spectroscopy

Scientific paper

Natural radiative lifetimes have been measured along the 6sns 3S1 (n=7-10) and 6snd 3D1 (n=6-11) Rydberg series of neutral mercury using time-resolved laser-induced fluorescence spectroscopy in a laser-produced mercury plasma. The states of Hg I investigated in the present work were populated from the ground state by a stepwise excitation process. Relativistic Hartree-Fock calculations, including intravalence interactions and core-polarization effects, have been performed and the theoretical lifetimes have been compared with the measurements.

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