Quasirelativistic formulation of the quantum-defect-orbital method

Physics

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Electron Orbitals, Quantum Theory, Relativistic Effects, Copper, Isoelectronic Sequence, Lithium, Oscillator Strengths, Sodium

Scientific paper

The quantum-defect-orbital method has been reformulated in order to include a major part of the relativistic effects. The resulting quasi-relativistic approach retains the simplicity of the original formulation but leads to more reliable results, particularly for the highly ionized atoms. The theory is illustrated by a series of calculations of oscillator strengths for the resonance transitions in atoms of lithium, sodium, and copper isoelectronic sequences.

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