Quantum mechanical electronic width and shift of spectral lines over the full line profile-electronic asymmetry

Details Quantum mechanical electronic width and shift of spectral lines over the full line profile-electronic asymmetry Quantum mechanical electronic width and shift of spectral lines over the full line profile-electronic asymmetry

Dec 1994

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1994jqsrt..52..819g&link_type=abstract

Journal of Quantitative Spectroscopy & Radiative Transfer (ISSN 0022-4073), vol. 52, no. 6, p. 819-824

Physics

10

Asymmetry, Electron States, Energy Levels, Line Spectra, Quantum Mechanics, Approximation, Hydrogen, Spectrum Analysis

Scientific paper

The electronic contributions to the asymmetry of spectral lines are investigated by considering frequency-dependent electronic widths and shifts. The asymmetry due to the frequency-dependent electronic width leads to increased blue line wings. The asymmetry of the line profile resulting from the shifts depends on the energy difference between the considered energy level and perturbing ones. For hydrogen lines the red wings are shifted to the red side whereas the blue wings are shifted to the blue side.

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