Quantitative dependence of crystallinity on degree of branching for hyperbranched poly[3-ethyl-3-(hydroxymethyl)oxetane]

Physics

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Scientific paper

A series of hyperbranched poly[3-ethyl-3-(hydroxymethyl)oxetane] samples with various degrees of branching (DB) were adopted to investigate the relationship between crystallinity and DB. The relative degree of crystallization (DC) and DB were determined by x-ray diffraction (XRD) and 13C nuclear magnetic resonance (13C-NMR) measurements, respectively. The corresponding plot of DC versus DB shows quantitative dependence of the crystallinity on DB for the polyether.

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