Q branches in the rotational spectrum of HOCl

Details Q branches in the rotational spectrum of HOCl Q branches in the rotational spectrum of HOCl

Jan 1983

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1983jqsrt..29...81c&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 29, Jan. 1983, p. 81-84. Research supported by the Chemical Ma

Computer Science

3

Acids, Atmospheric Chemistry, Infrared Spectra, Molecular Spectra, Rotational Spectra, Stratosphere, Chlorine Compounds, Far Infrared Radiation, Fourier Transformation, Line Spectra, Molecular Oscillations, Optical Transition, Ozone, Pollution Monitoring

Scientific paper

The far IR rotational spectrum of HOCl from 70-263/cm have been obtained. The most prominent features of the rotational spectrum are the Q branches, for which positions have been measured. Statistical strengths for the Q branches have been calculated and mu sub b, the component of the dipole moment that allows Q branch transitions, has been determined from P and R branch line intensities. It is found that mu sub b = 1.4 + or - 0.2 D. Q branch strengths and shifts at stratospheric temperature are calculated.

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