Q-branch shapes of CO2 spectrum in 15 μm region: experiment.

Details Q-branch shapes of CO2 spectrum in 15 μm region: experiment. Q-branch shapes of CO2 spectrum in 15 μm region: experiment.

Mar 1996

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996jqsrt..55..321t&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 55, issue 3, pp. 321-334

Physics

17

Carbon Dioxide: Infrared Spectra, Carbon Dioxide: Laboratory Spectra

Scientific paper

The shapes of Q-branches in CO2 spectra in the 580-850 cm-1 region for pure gas and mixtures CO2-He and CO2-Ar have been studied at resolutions up to 0.002 cm-1. The branch broadening coefficients were measured in the pressure range from a few torr to 50 atm. Those for 11102-02201 Π-Δ transition are different for pressures below and above 5 atm. At higher pressures the branch broadening coefficients are similar for all Q-branches. The observed Q-branch shape transformation is explained by line mixing effects.

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