Prospects for the involvement of transition metals in the chemistry of diffuse interstellar clouds: formation of FeH+ by radiative association.

Physics

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Interstellar Clouds: Molecular Processes

Scientific paper

Transition metals traditionally have been ignored in chemical models of interstellar clouds. Thermochemical considerations indicate that the formation of several important species can be catalyzed by transition metal ions. The importance of such chemistry depends critically upon the rate of conversion of atomic metal ions into molecular species. Potential energy curves and transition moments have been calculated and a simple model employed to determine the rate constant for the appropriate reaction of iron, FeH+ formation by radiative association.

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