Properties of solid and gaseous hydrogen, based upon anisotropic pair interactions

Details Properties of solid and gaseous hydrogen, based upon anisotropic pair interactions Properties of solid and gaseous hydrogen, based upon anisotropic pair interactions

Nov 1975

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1975phrva..12.2199e&link_type=abstract

Physical Review A - General Physics, 3rd Series, vol. 12, Nov. 1975, p. 2199-2212.

Physics

General Physics

32

Deuterium, Ground State, Hydrogen, Ortho Hydrogen, Para Hydrogen, Solidified Gases, Anisotropy, High Pressure, Low Pressure, Orbitals, Perturbation Theory, Virial Theorem

Scientific paper

Properties of H2 are studied on the basis of an analytic anisotropic potential deduced from atomic orbital and perturbation calculations. The low-pressure solid results are based on a spherical average of the anisotropic potential. The ground state energy and the pressure-volume relation are calculated. The metal-insulator phase transition pressure is predicted. Second virial coefficients are calculated for H2 and D2, as is the difference in second virial coefficients between ortho and para H2 and D2.

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