Physics – Plasma Physics
Scientific paper
Jun 2000
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2000jgr...10512833c&link_type=abstract
Journal of Geophysical Research, Volume 105, Issue A6, p. 12833-12838
Physics
Plasma Physics
6
Atmospheric Composition And Structure: Chemical Kinetic And Photochemical Properties, Atmospheric Composition And Structure: Thermosphere-Composition And Chemistry, Space Plasma Physics: Laboratory Studies, Space Plasma Physics: Spacecraft/Atmosphere Interactions
Scientific paper
Reactions involving fast nitrogen atoms are of importance both in the upper atmosphere and in defining the near-field environment around orbiting spacecraft. We present the first quantitative study of the distribution of vibrationally excited ground state NO produced in the reaction of 8 km/s N atoms with O2. A pulsed beam of energetic nitrogen atoms was interacted with thermal oxygen molecules under single-collision conditions in a crossed beam configuration. The fundamental and first overtone band emissions of the reaction product NO (X2Π) were measured using both band-pass-filtered radiometers and a circular variable filter. The spectrally resolved emissions were analyzed to determine the nascent NO vibrational distribution and the vibrational state-specific reaction cross sections. The present results are compared with earlier measurements performed at thermal energies and contrasted with theoretical predictions.
Blumberg A. M. W.
Caledonia George E.
Krech R. H.
Lipson Steven J.
Oakes D. B.
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