Pressure dependency for heavy isotope enhancement in ozone formation

Details Pressure dependency for heavy isotope enhancement in ozone formation Pressure dependency for heavy isotope enhancement in ozone formation

May 1990

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1990georl..17..717t&link_type=abstract

Geophysical Research Letters (ISSN 0094-8276), vol. 17, May 1990, p. 717-719.

Physics

51

Formation, Heavy Ions, Isotopic Enrichment, Ozone Depletion, Pressure Dependence, Chemical Fractionation, Complex Compounds, Life (Durability), Oxygen 17, Oxygen 18, Reaction Kinetics

Scientific paper

Consideration is given to the O-18, O-17 mass independent isotopic enrichment that accompanies O3 formation. In order to study the potential role of the activated complex liftime, the effect of pressure in the region where third body kinetic fall-off occurs is measured. The decrease in O3-(O-18) enrichment with increasing pressure initiates at a lower pressure than predicted by the reaction order pressure dependency.

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