Physics
Scientific paper
May 1988
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1988jqsrt..39..271l&link_type=abstract
Journal of Quantitative Spectroscopy and Radiative Transfer (ISSN 0022-4073), vol. 39, May 1988, p. 271-282.
Physics
15
Oxygen Spectra, Pressure Broadening, Schumann-Runge Bands, Spectral Line Width, Absorption Spectra, Molecular Rotation, Vibrational Spectra
Scientific paper
The pressure-broadened widths for selected rotational lines from the (2-0) to (15-0) Schumann-Runge bands of O2 have been measured at pressures up to 60 atm. The self-broadening coefficient exhibits no dependence on rotation and a small dependence on vibration, in agreement with theoretical expectations, and may be taken as 0.20/cm atm FWHM, implying an optical collision diameter of 6.2A. The broadened absorption lines are shifted towards longer wavelenghts and are asymmetric with a steeper blue wing, both of these effects increasing with pressure.
Berzins L.
Dedman C. J.
Lewis Brenton R.
Scholz T. T.
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