Pressure Broadening and Pressure Shift of Diatomic Iodine at 675 nm

Details Pressure Broadening and Pressure Shift of Diatomic Iodine at 675 nm Pressure Broadening and Pressure Shift of Diatomic Iodine at 675 nm

2009-10-27

arxiv.org/abs/0910.5053v1

Physics

Chemical Physics

Ph.D. dissertation

Scientific paper

Pressure broadening and pressure shift coefficients for 127I2 (diatomic iodine) in the presence of various buffer gases were determined respectively from the line-widths and line-center shifts observed in Doppler-limited, steady-state, linear absorption spectra near 675 nm as a function of buffer gas pressure through a nonlinear regression analysis of observed line shapes against a Gaussian-Lorentzian convolution line shape model. A line shape model, obtained from a first-order perturbation solution of the time-dependent Schrodinger equation for randomly occurring interactions between a two-level system and a buffer gas treated as step-function potentials, reveals a relationship between the ratio of pressure broadening to pressure shift coefficients and a change in the wave function phase-factor, interpreted as reflecting the "cause and effect" of state-changing events in the microscopic domain. Collision cross-sections determined from this model are interpreted as reflecting the inelastic nature of collision-induced state-changing events. A steady-state kinetic model for the two-level system compatible with the Beer-Lambert law reveals thermodynamic constraints on the ensemble-average state-changing rates and collision cross-sections, and leads to the proposal of a relationship between observed asymmetric line shapes and irreversibility in the microscopic domain, and suggests that such features may be more fully consistent with the use of non-Hermitian Hamiltonians for describing the state-changing process; in the context of the [non-degenerate] two-level model, the Hamiltonian that describes photon absorption is not the Hermitian conjugate of the Hamiltonian that describes photon emission.

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