Predictions for collisional broadening of far-infrared OH rotational lines of atmospheric interest

Physics – Optics

Scientific paper

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Far Infrared Radiation, Hydroxyl Radicals, Hyperfine Structure, Molecular Collisions, Molecular Rotation, Spectral Line Width, Nitrogen, Temperature Dependence

Scientific paper

Collisional line shapes for OH in the presence of N2 are computed using the Anderson theory. The theoretical results compare satisfactorily with the experimental results now available. Predictions for all strong OH far-infrared lines are given together with the dependence of broadening and shift on temperature. The results will be useful in the interpretation of atmospheric or astrophysical spectra.

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