Possible existence and role of excited ozone precursors in the stratosphere

Details Possible existence and role of excited ozone precursors in the stratosphere Possible existence and role of excited ozone precursors in the stratosphere

Apr 1979

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1979p%26ss...27..411p&link_type=abstract

Planetary and Space Science, vol. 27, Apr. 1979, p. 411-417. Research supported by the Australian Research Grants Commission

Physics

1

Atmospheric Radiation, Ozone, Quantum Theory, Stratosphere, Upper Atmosphere, Heat Balance, Metastable State, Photochemical Reactions, Reaction Kinetics

Scientific paper

Laboratory kinetic experiments, quantum theoretical studies and certain recently discovered infrared emissions from the stratosphere together imply the possible existence of a metastable, energetic, and reactive form of ozone in the upper atmosphere. This species can potentially affect the upper atmospheric photochemistry and heat balance. For these reasons there is a need for further quantum theoretical and laboratory chemical kinetic studies addressing some of the relevant properties of the internally excited ozone precursors.

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