Plasma Kinetics in the Ethanol/Water/Air Mixture in "Tornado" Type Electrical Discharge

Physics – Plasma Physics

Scientific paper

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27 pages, 14 figures, 3 tables, accepted for publication in Journal of Physics D

Scientific paper

10.1088/0022-3727/44/14/145206

This paper presents the results of a theoretical and experimental study of plasma-assisted reforming of ethanol into molecular hydrogen in a new modification of the "tornado" type electrical discharge. Numerical modeling clarifies the nature of the non-thermal conversion and explains the kinetic mechanism of nonequilibrium plasma-chemical transformations in the gas-liquid system and the evolution of hydrogen during the reforming as a function of discharge parameters and ethanol-to-water ratio in the mixture. We also propose a scheme of chemical reactions for plasma kinetics description. It is shown that some characteristics of the investigated reactor are at least not inferior to characteristics of other plasma chemical reactors.

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