Photoelectron spectroscopy of the halogen oxide anions FO(-), ClO(-), BrO(-), IO(-), OClO(-), and OIO(-)

Details Photoelectron spectroscopy of the halogen oxide anions FO(-), ClO(-), BrO(-), IO(-), OClO(-), and OIO(-) Photoelectron spectroscopy of the halogen oxide anions FO(-), ClO(-), BrO(-), IO(-), OClO(-), and OIO(-)

Jun 1992

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1992jchph..96.8012g&link_type=abstract

Journal of Chemical Physics (ISSN 0021-9606), vol. 96, no. 11, June 1, 1992, p. 8012-8020.

Physics

Chemical Physics

47

Anions, Franck-Condon Principle, Halogen Compounds, Photoelectron Spectroscopy, Vibration Mode, Electron Affinity, Heat Of Formation, Molecular Structure, Oxides, Thermochemistry, Vibrational Spectra

Scientific paper

The study reports the 351-nm photoelectron spectra of FO(-), ClO(-), BrO(-), IO(-), OClO(-), and OIO(-). Anion vibrational frequencies are observed in the spectra, and bond lengths are obtained for the anions from Franck-Condon simulations. Spectra of the halogen dioxides display two active vibrational modes - the symmetric stretch and the bend. Anion symmetric stretching frequencies and normal coordinate displacements from the corresponding neutral are reported.

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