Physics – Chemical Physics
Scientific paper
Sep 1991
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1991jchph..95.4723g&link_type=abstract
Journal of Chemical Physics (ISSN 0021-9606), vol. 95, Sept. 15, 1991, p. 4723, 4724.
Physics
Chemical Physics
13
Electron Affinity, Electron Transitions, Energy Spectra, Franck-Condon Principle, Iodine Compounds, Photoelectron Spectroscopy, Ground State, Molecular Energy Levels, Quantum Chemistry, Spin-Orbit Interactions, Ultraviolet Radiation
Scientific paper
The IO(2Pi3/2,2Pi1/2;v-prime) + e(-) - IO(-)(1Sigma/+/;v-double prime) spectrum is obtained via photoelectron spectroscopy. The 351.1 nm photoelectron spectrum of IO(-) taken at the 'magic angle' is shown. Unknown molecular constants for IO(-) and IO are determined from Franck-Condon simulations of the spectrum for each of the electronic transitions observed.
Gilles Mary K.
Lineberger Carl W.
Polak Mark L.
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