Photodissociation of Methyl Nitrite from the s2 State -- Ion Images and Vector Correlations

Physics

Scientific paper

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Dynamics

Scientific paper

Methyl nitrite, CH3ONO, was photodissociated near 225 nm in a
velocity-mapping time-of-flight mass spectrometer. The NO photoproduct
was detected through state-resolved 1+1' resonance-enhanced multiphoton
ionization. The NO products are highly oriented in the laboratory frame,
indicating a parallel transition and a fast dissociation.

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