Physics
Scientific paper
Jun 1999
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1999georl..26.1695l&link_type=abstract
Geophysical Research Letters, Volume 26, Issue 12, p. 1695-1698
Physics
5
Atmospheric Composition And Structure: Chemical Kinetic And Photochemical Properties, Atmospheric Composition And Structure: Cloud Physics And Chemistry, Atmospheric Composition And Structure: Constituent Sources And Sinks
Scientific paper
The destruction of ozone on ice surfaces was studied with an ice-coated fused silica column used as a very long flow tube. Ozone destruction was found to be very slow. At 223 K and 258 K the measured reaction probabilities fall in the range 2×10-8-4×10-10, decreasing with increasing ozone concentration (20-1000 nbar). The observed kinetics are explained by an at least two step mechanism. The low reaction rates observed are insignificant for ozone destruction in cirrus clouds.
Langenberg Stefan
Schurath Ulrich
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