Ozone destruction on ice

Physics

Scientific paper

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Atmospheric Composition And Structure: Chemical Kinetic And Photochemical Properties, Atmospheric Composition And Structure: Cloud Physics And Chemistry, Atmospheric Composition And Structure: Constituent Sources And Sinks

Scientific paper

The destruction of ozone on ice surfaces was studied with an ice-coated fused silica column used as a very long flow tube. Ozone destruction was found to be very slow. At 223 K and 258 K the measured reaction probabilities fall in the range 2×10-8-4×10-10, decreasing with increasing ozone concentration (20-1000 nbar). The observed kinetics are explained by an at least two step mechanism. The low reaction rates observed are insignificant for ozone destruction in cirrus clouds.

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