Oxygen singlet Delta 1.58-micrometer (0-1) limb radiance in the upper stratosphere and lower mesosphere

Physics

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Infrared Spectroscopy, Mesosphere, Oxygen Spectra, Stratosphere, Earth Limb, Night Sky, Photochemical Reactions, Radiance, Rocket Flight, Two Dimensional Models, Vertical Distribution

Scientific paper

The SPIRE (Spectral Infrared Rocket Experiment) rocket-borne infrared limb measurements of the O2 (1 Delta g) (0-1) band are examined and compared to the radiance predicted by a two-dimensional photochemical model for ozone and O2 (1 Delta g) concentration. A simple one-dimensional onion peel inversion is used to show that a value of A(0,1) = 5.0 x 10 to the -6th/s is needed to yield reasonable O2 (1 Delta g) densities. The photochemistry of O2 (1 Delta g) is discussed, and a photochemical model that successfully simulates the SPIRE 1.58 micron radiance profiles is described.

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