Oxygen isotope exchange between illite and water at 22°C

Physics

Scientific paper

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Scientific paper

Oxygen isotope exchange experiments at 22°C have been made on a series of illites displaying a range of perfection of crystallinity and degree of interstratification. Structurally bound oxygen underwent significant non-equilibrium exchange in time periods ranging from 2 to 70 months. Exchange was found to be controlled by accessibility of water to the interlayer cation region. 1000 In appears to be in the general neighborhood of +23.4 at 22°C for the illite-water system; however, it was found that equilibrium fractionation cannot be represented by a single value for structurally and chemically distinct illites.

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