Oscillator strengths for the Schumann-Runge bands of (O-16)2

Details Oscillator strengths for the Schumann-Runge bands of (O-16)2 Oscillator strengths for the Schumann-Runge bands of (O-16)2

Sep 1986

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1986jqsrt..36..209l&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer (ISSN 0022-4073), vol. 36, Sept. 1986, p. 209-232.

Physics

54

Dipole Moments, Oscillator Strengths, Oxygen, Photodissociation, Schumann-Runge Bands, Spectral Line Width, Absorption Spectra, Doppler Effect, Exponential Functions, Lorentz Force

Scientific paper

Experimental oscillator strengths are presented for the (1-0)-(22-0) and (3-1)-(17-1) Schumann-Runge bands of (O-16)2. A wavelength resolution of about 4 pm enabled individual rotational lines to be studied, and an equivalent-width data analysis method was used. The now established decrease in equivalent band oscillator strength with increased rotation is observed. The mean band oscillator strengths for the (1-0)-(12-0) bands are in excellent agreement with recent ultra-high-resolution absolute measurements, and the oscillator strength density is found to be continuous across the dissociation limit. The dipole moment deduced from the present oscillator strengths agrees well with recent ab initio and semiempirical determinations.

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