Physics – Atomic Physics
Scientific paper
Jul 2004
adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=2004ycat..34260717t&link_type=abstract
VizieR On-line Data Catalog: J/A+A/426/717. Originally published in: 2004A&A...426..717T
Physics
Atomic Physics
Atomic Physics
Scientific paper
Non-orthogonal orbitals technique in the multiconfiguration Hartree-Fock approach is used to calculate oscillator strengths and transition probabilities for allowed and intercombination lines in Cl II. The relativistic corrections are included through the Breit-Pauli Hamiltonian. The Cl II wave functions show strong term dependence. The non-orthogonal orbitals are used to describe the term dependence of radial functions. Large sets of spectroscopic and correlation functions are chosen to describe adequately strong interactions in the 3s2 3p3nl 3Po, 1Po and 3Do Rydberg series and to properly account for the important correlation and relaxation effects. The length and velocity forms of oscillator strength show good agreement for most transitions.
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