Ortho and Para Molecules of Water in Electric Field

Details Ortho and Para Molecules of Water in Electric Field Ortho and Para Molecules of Water in Electric Field

2007-03-04

arxiv.org/abs/physics/0703038v1

Physics

Chemical Physics

4 pages, 2 figures

Scientific paper

Stark effect is calculated by the perturbation theory method separately for the ortho and para water molecules. At room temperature, a 30%-difference in the energy change is found for the two species put in electric field. This implies a sorting of the ortho and para water molecules in non-uniform electric fields. The ortho/para water separation is suggested to occur in the course of steam sorption on a solid surface and of large-scale atmospheric processes.

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