Optical spectra of size-selected mercury cluster ions

Physics

Scientific paper

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Scientific paper

Optical absorption spectra for size-selected Hgn+ and Hgn++ clusters show an abrupt transition to a collective, plasmon-like absorption as a function of increasing cluster size. The position of the one plasmon peak as well as the width of the plasmon peak is studied in detail. A temperature dependence is conjectured for the width. A strong influence of electronic correlations on the cluster size dependence of the oscillator strength is observed.

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