Optical second harmonic generation probe of two-dimensional ferroelectricity

Physics – Optics

Scientific paper

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9 pages, 2 figures, Optics Letters, in print

Scientific paper

10.1364/OL.25.000411

Optical second harmonic generation (SHG) is used as a noninvasive probe of two-dimensional (2D) ferroelectricity in Langmuir-Blodgett (LB) films of copolymer vinylidene fluoride with trifluorethylene. The surface 2D ferroelectric-paraelectric phase transition in the topmost layer of LB films and a thickness independent (almost 2D) transition in the bulk of these films are observed in temperature studies of SHG.

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