On the nature of collision-induced absorption in gaseous homonuclear diatomics.

Details On the nature of collision-induced absorption in gaseous homonuclear diatomics. On the nature of collision-induced absorption in gaseous homonuclear diatomics.

Sep 1996

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1996jqsrt..56..409v&link_type=abstract

Journal of Quantitative Spectroscopy and Radiative Transfer, vol. 56, issue 3, pp. 409-422

Physics

12

Radiative Transfer: Atmospheres

Scientific paper

The phenomenon of collision-induced absorption in equilibrium gases is considered by accounting for the statistical - physical partitioning of bound, metastable and free bimolecular states. The importance of molecular anisotropy and dimers formation is emphasized. A line-mixing model is suggested to describe the overall collision-induced bandshapes of nitrogen and oxygen fundamentals, which effectively accounts for the perturbation of monomers rotational movement.

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