On the dynamics and thermodynamics of small Markov-type material systems

Details On the dynamics and thermodynamics of small Markov-type material systems On the dynamics and thermodynamics of small Markov-type material systems

2008-05-07

arxiv.org/abs/0805.0944v2

Physics

Mathematical Physics

Keywords: activation energy, asymptotical stability, diathermal boundary, energy barrier, irreversible process, isothermal pro

Scientific paper

Collective properties of material systems with the dynamics described by semidynamical systems and revealing the Markov-type irreversible evolution, are investigated. It is assumed that these material systems admit their treatment as thermodynamic systems in diathermal and isothermal conditions. A kinetic equation describing statistical regularities of the Markov-type material systems and constrained by the compatibility condition with the first and second laws of thermodynamics and with the relaxation postulate, is proposed. It is pointed out that the proposed method of the description of collective properties of the material systems can be helpful for better understanding of the nonequilibrium thermodynamics of small material systems.

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