Olivine-Spinel transformation in a natural forsterite

Physics

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Scientific paper

The olivine-spinel transformation in a natural forsterite is studied in the pressure range 98-130 kb and the temperature range 700-1100 °C. The reaction boundary at which olivine solid solution of 93% Mg2SiO4 and 7% Fe2SiO4 breaks down to spinel solid solution and olivine solid solution is determined as P(kb) = 0.054T(°C)+61. The entropy change of the metastable olivine-spinel transformation in pure Mg2SiO4 is calculated to be - 4.4 cal/° . mole at 100 kb and 1000 °C.

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