Odd nitrogen removal on background sulfate aerosols - Implications for the ozone hole

Computer Science – Numerical Analysis

Scientific paper

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Aerosols, Atmospheric Chemistry, Nitrogen Oxides, Ozone Depletion, Sulfates, Nitric Acid, Numerical Analysis, Removal, Stratosphere, Two Dimensional Models

Scientific paper

A sensitivity study is carried out for the dependence of the polar ozone loss rate on the value of the sticking coefficient gamma for the reaction converting odd nitrogen into nitric acid on sulfate aerosols. In this study, a 2D model including nitrogen and chlorine families is used along with an explicit condensation mechanism for polar stratospheric clouds (PSC) and a fixed distribution of background sulfate aerosols in the lower stratosphere. If only background aerosols are included, negligible changes in total ozone are observed (up to about 1 percent) when gamma is increased from 0.02 to 0.14. If PSCs are added, the same test produces a significant reduction of the ozone hole depth in Antarctica.

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