Observations of the nighttime abundance of OClO in the winter stratosphere above Thule, Greenland

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Atmospheric Chemistry, Chlorine Oxides, Ozone Depletion, Polar Regions, Stratosphere, Diurnal Variations, Greenland, Ice Clouds, Night, Nitrogen Oxides, Photolysis, Winter

Scientific paper

Observations at Thule, Greenland, that made use of direct light from the moon on February 2, 3, 4, 5, and 7, 1988 revealed nighttime chlorine dioxide (OClO) abundances that were less than those obtained in Antarctica by about a factor of 5, but that exceeded model predictions based on homogeneous (gas-phase) photochemistry by about a factor of 10. These data suggest that heterogeneous (surface) reactions due to polar stratospheric clouds can occur in the Arctic, providing a mechanism for possible Arctic ozone depletion.

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