Observation of the infrared spectrum of the hydrogen molecular ion HD/+/

Details Observation of the infrared spectrum of the hydrogen molecular ion HD/+/ Observation of the infrared spectrum of the hydrogen molecular ion HD/+/

Jun 1976

adsabs.harvard.edu/cgi-bin/nph-data_query?bibcode=1976phrvl..36.1488w&link_type=abstract

Physical Review Letters, vol. 36, June 21, 1976, p. 1488-1491. Research supported by the Research Corp., U.S. Air Force, NSF, an

Physics

135

Hydrogen Ions, Infrared Spectra, Molecular Energy Levels, Molecular Ions, Molecular Spectra, Vibrational Spectra, Deuterides, Hyperfine Structure, Molecular Rotation, Optical Resonance, Rotational Spectra

Scientific paper

The vibration-rotational spectrum of the hydrogen molecular ion HD(+) has been observed by means of an ion-beam laser-resonance method employing Doppler-effect tuning and collisional detection. Six transition-frequency groups between 1642 and 1869 kaysers, exhibiting partially resolved hyperfine structure, have been measured to within + or - 1 ppm. The accuracy exceeds that of present theoretical calculations of HD(+) energy levels.

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